Preparation and solid state characterization of 1,2,3,5-diselenadiazolyl [HCN2Se2].

A. Wallace Cordes; Sivert H. Glarum; Robert C. Haddon; Randal Hallford; Robin G. Hicks; Dietmar K. Kennepohl; Richard T. Oakley; Thomas T.M. Palstra; Syrona R. Scott

doi:10.1039/C39920001265

Preparation and solid state characterization of 1,2,3,5-diselenadiazolyl [HCN₂Se₂]^.

A. Wallace Cordes
, Sivert H. Glarum
, Robert C. Haddon
, Randal Hallford
, Robin G. Hicks
, Dietmar K. Kennepohl
, Richard T. Oakley
, Thomas T.M. Palstra
, Syrona R. Scott

Centre for Science

University of Arkansas, Fayetteville
Nokia
University of Guelph

Research output: Contribution to journal › Journal Article › peer-review

28 Citations (Scopus)

Abstract

The reaction of N,N,N′-tris(trimethylsilyl)formamidine with SeCl ₂ affords 1,2,3,5-diselenadiazolium chloride, which can be reduced with triphenylantimony to the corresponding diselenadiazolyl radical [HCN ₂Se₂]^.; the solid state structure and conductivity of the dimer [HCN₂Se₂]₂ are reported.

Original language	English
Pages (from-to)	1265-1266
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/C39920001265
Publication status	Published - 1 Jan. 1992

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10.1039/C39920001265

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@article{4586696ce61e42a692fb6eba93736ead,

title = "Preparation and solid state characterization of 1,2,3,5-diselenadiazolyl [HCN2Se2].",

abstract = "The reaction of N,N,N′-tris(trimethylsilyl)formamidine with SeCl 2 affords 1,2,3,5-diselenadiazolium chloride, which can be reduced with triphenylantimony to the corresponding diselenadiazolyl radical [HCN 2Se2].; the solid state structure and conductivity of the dimer [HCN2Se2]2 are reported.",

author = "Cordes, \{A. Wallace\} and Glarum, \{Sivert H.\} and Haddon, \{Robert C.\} and Randal Hallford and Hicks, \{Robin G.\} and Kennepohl, \{Dietmar K.\} and Oakley, \{Richard T.\} and Palstra, \{Thomas T.M.\} and Scott, \{Syrona R.\}",

year = "1992",

month = jan,

day = "1",

doi = "10.1039/C39920001265",

language = "English",

pages = "1265--1266",

number = "17",

}

TY - JOUR

T1 - Preparation and solid state characterization of 1,2,3,5-diselenadiazolyl [HCN2Se2].

AU - Cordes, A. Wallace

AU - Glarum, Sivert H.

AU - Haddon, Robert C.

AU - Hallford, Randal

AU - Hicks, Robin G.

AU - Kennepohl, Dietmar K.

AU - Oakley, Richard T.

AU - Palstra, Thomas T.M.

AU - Scott, Syrona R.

PY - 1992/1/1

Y1 - 1992/1/1

N2 - The reaction of N,N,N′-tris(trimethylsilyl)formamidine with SeCl 2 affords 1,2,3,5-diselenadiazolium chloride, which can be reduced with triphenylantimony to the corresponding diselenadiazolyl radical [HCN 2Se2].; the solid state structure and conductivity of the dimer [HCN2Se2]2 are reported.

AB - The reaction of N,N,N′-tris(trimethylsilyl)formamidine with SeCl 2 affords 1,2,3,5-diselenadiazolium chloride, which can be reduced with triphenylantimony to the corresponding diselenadiazolyl radical [HCN 2Se2].; the solid state structure and conductivity of the dimer [HCN2Se2]2 are reported.

UR - https://www.scopus.com/pages/publications/37049087026

U2 - 10.1039/C39920001265

DO - 10.1039/C39920001265

M3 - Journal Article

AN - SCOPUS:37049087026

SN - 0022-4936

SP - 1265

EP - 1266

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 17

ER -

Preparation and solid state characterization of 1,2,3,5-diselenadiazolyl [HCN₂Se₂]^.

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